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Apr 27, 2016· Engineering Thermodynamics Lecture Notes 1. VEER SURENDRA SAI UNIVERSITY OF TECHNOLOGY BURLA, ODISHA DEPARTMENT OF MECHANICAL ENGINEERING ENGINEERING THERMODYNAMICS Lecture Notes 2. Disclaimer This document does not claim any originality and cannot be used as a substitute for prescribed textbooks.
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Helmoltz free energy, F = UTS; Enthalpy, H = U+pv and Gibbs free energy, G =U+pvTS. The electrolysis of one mole of water produces a mole of hydrogen gas and a half a mole of oxygen gas in their normal diatomic forms. A detailed analysis of this process makes use of the thermodynamic potentials and the first law of thermodynamics.
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The principle of detailed balance is shown to be a sufficient condition for the second law of thermodynamics in thermally equilibrated elementary chemical reactions. For an elementary reaction, the principle of detailed balance relates the forward and the reverse rate constants through the reaction equilibrium constant.
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The First Law of Thermodynamics Work and heat are two ways of transfering energy between a system and the environment, causing the system's energy to change. If the system as a whole is at rest, so that the bulk mechanical energy due to translational or rotational motion is zero, then the
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In the polytropic process we have pvn = constant, if the value of n is infinitely large, the process is called constant volume process. The molecular volume of any perfect gas .
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